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Acetic acid,2-(trimethylsilyl)-, methyl ester CAS NO.2916-76-9
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Keywords
- Aceticacid, (trimethylsilyl)-, methyl ester (7CI,8CI,9CI)
- ethyl2-(trimethylsilyl)acetate
- NSC 601813
Quick Details
- ProName: Acetic acid,2-(trimethylsilyl)-, methy...
- CasNo: 2916-76-9
- Application: The Acetic acid,2-(trimethylsilyl)-, m...
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- Purity: 99
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Superiority
The Acetic acid,2-(trimethylsilyl)-, methyl ester, with the CAS registry number 2916-76-9, is also known as Methyl trimethylsilylacetate. It belongs to the product categories of C6 to C7; Carbonyl Compounds; Esters. Its EINECS registry number is 220-845-0. This chemical's molecular formula is C6H14O2Si and molecular weight is 146.26. Its systematic name is called methyl (trimethylsilyl)acetate.
Physical properties of Acetic acid,2-(trimethylsilyl)-, methyl ester: (1)ACD/LogP: 1.73; (2)ACD/LogD (pH 5.5): 1.73; (3)ACD/LogD (pH 7.4): 1.73; (4)ACD/BCF (pH 5.5): 12.08; (5)ACD/BCF (pH 7.4): 12.08; (6)ACD/KOC (pH 5.5): 207.12; (7)ACD/KOC (pH 7.4): 207.12; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Index of Refraction: 1.398; (11)Molar Refractivity: 40.33 cm3; (12)Molar Volume: 166.7 cm3; (13)Surface Tension: 20.4 dyne/cm; (14)Density: 0.876 g/cm3; (15)Flash Point: 23.1 °C; (16)Enthalpy of Vaporization: 37.8 kJ/mol; (17)Boiling Point: 140.8 °C at 760 mmHg; (18)Vapour Pressure: 6.02 mmHg at 25°C.
Preparation: this chemical can be prepared by iodo-trimethyl-silane and 1,1-dimethoxy-ethene. The yield is about 98%.
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Uses of Acetic acid,2-(trimethylsilyl)-, methyl ester: it can be used to produce 3-hydroxy-3-phenyl-2-trimethylsilanyl-propionic acid methyl ester at temperature of -80 °C. This reaction will need reagent LDA, MgBr2 and solvent tetrahydrofuran. The yield is about 78%.
Details
The Acetic acid,2-(trimethylsilyl)-, methyl ester, with the CAS registry number 2916-76-9, is also known as Methyl trimethylsilylacetate. It belongs to the product categories of C6 to C7; Carbonyl Compounds; Esters. Its EINECS registry number is 220-845-0. This chemical's molecular formula is C6H14O2Si and molecular weight is 146.26. Its systematic name is called methyl (trimethylsilyl)acetate.
Physical properties of Acetic acid,2-(trimethylsilyl)-, methyl ester: (1)ACD/LogP: 1.73; (2)ACD/LogD (pH 5.5): 1.73; (3)ACD/LogD (pH 7.4): 1.73; (4)ACD/BCF (pH 5.5): 12.08; (5)ACD/BCF (pH 7.4): 12.08; (6)ACD/KOC (pH 5.5): 207.12; (7)ACD/KOC (pH 7.4): 207.12; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Index of Refraction: 1.398; (11)Molar Refractivity: 40.33 cm3; (12)Molar Volume: 166.7 cm3; (13)Surface Tension: 20.4 dyne/cm; (14)Density: 0.876 g/cm3; (15)Flash Point: 23.1 °C; (16)Enthalpy of Vaporization: 37.8 kJ/mol; (17)Boiling Point: 140.8 °C at 760 mmHg; (18)Vapour Pressure: 6.02 mmHg at 25°C.
Preparation: this chemical can be prepared by iodo-trimethyl-silane and 1,1-dimethoxy-ethene. The yield is about 98%.
Uses of Acetic acid,2-(trimethylsilyl)-, methyl ester: it can be used to produce 3-hydroxy-3-phenyl-2-trimethylsilanyl-propionic acid methyl ester at temperature of -80 °C. This reaction will need reagent LDA, MgBr2 and solvent tetrahydrofuran. The yield is about 78%.